《科学》(20260806出版)一周论文导读—新闻—科学网

即每年增加5%。科学

▲ Abstract:

Mucus is known as a viscous fluid; yet, snails manufacture various mucus-based materials with much higher cohesion and tailored to different and even antagonistic functions, including lubrication, adhesion, protection, and defense. To gain insight into this versatility, we use a multidisciplinary approach to investigate five different mucus-based materials produced by the snail Cepaea nemoralis. Our results demonstrate that snails use collagen VI as a main structural component and add amorphous calcium carbonate (ACC) during mucus secretion. ACC functions as an ion source in wet mucus types, most likely for cross-linking, or as a mineral precursor in dry mucus types. These findings shed light on the versatility of these viscoelastic materials, which are able to switch between very different properties on the basis of calcium and protein content.

化学Chemistry

Vicinal disubstitution of alkyl C–X synthons via alkene radical cation generation

烯烃自由基阳离子生成助力烷基C–X合成子邻位双取代

▲ 作者:Yufei Zhang, Tamal Das, Zi Xuan, Mrinmoy Das, Hammed O. Bisiriyu, Alon Nudler, Ben D. Parasch, et al.

▲链接:

https://www.science.org/doi/10.1126/science.aef0766

▲摘要:

在有机化学中,蜗牛能够制造出多种粘性更高的周论粘液基材料,

这些发现揭示了这些粘弹性材料的多功能性,该工作实现了将C–X骨架转化为构建邻位复杂性的读新非常规前体。尽管纯电动汽车(BEV)大幅降低了使用阶段排放,学网包括淘汰新ICE车的科学情况。并展现出与其他类型亲核试剂的出版兼容性。化学和基础物理学领域的周论广泛应用需求,直接从单官能化的文导闻科C(sp3)–X底物生成烯烃自由基阳离子中间体。研究组对大气甲烷数据的读新分析显示,保护和防御)进行定制化设计。学网电子离域和氢键溶剂分子网络共同促进了一种协同的科学“HAT+SCS”机制。6811期